By Arian Mostaedi
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Extra info for Architectural Design - EDUCATION AND CULTURE
Over the past ten years there has been much activity in the PVC industry aimed at preventing PVC deposits in the autoclave (build-up) which caused numerous problems and required interbatch autoclave cleaning. 5 but most companies now have chemical systems for controlling build-up formation such that very greatly reduced cleaning is required. 4g/ml) so that there is a large volume contraction in the autoclave contents. Advantage can be taken of this fact by increasing the initial VCM charge at the expense of the initial water SUSPENSION POLYMERISATION OF VINYL CHLORIDE 19 and injecting water during the polymerisation as the volume contracts.
16) In some plants both processes were used in tandem, the HC1 from the cracking of EDC being combined with acetylene. Since 1965 virtually all major new VCM plants have been based on a combination of direct chlorination and oxychlorination of ethylene, the so-called balanced process. In the first step EDC is produced by the direct chlorination of ethylene. 17) In the second step the purified EDC is pyrolysed to give VCM and HC1. 18) In the third step this HC1, mixed with air or oxygen, is reacted with ethylene to form further amounts of EDC.
Appl. Polym. , 16, 783 (1972). , GARDINOVACKI, B. , Pure Appl. Chem, 26, 121 (1971). J. , Polym. Sci. USSR, 15, 2712 (1974). FREEMAN, M. , J. Polym. , A2, 2017 (1964). MONSANTO, British Patent 954983. N. , J. Amer. Chem. , 49,2801 (1927). , Ind. J. , 2, 125 (1964). , TAKCUCHI, K. , J. Polym. , Polymer Chem. , 10, 2841 (1972). A. , J. Polym. , Polymer Phys. , 18, 51 (1980). , Brit. Polym. , 12, 186 (1980). , J. Macromol. , A11(7), 1205 (1977). W. B. ), Mixing Theory and Practice, Volume 2, Academic Press, London (1967).
Architectural Design - EDUCATION AND CULTURE by Arian Mostaedi